Covalent bonds

Sharing a pair of electrons

When two hydrogen atoms come close together, each atom provides its single electron, and the two electrons form a pair that both atoms share.

The shared pair is attracted by both nuclei, and this holds the two atoms together as a hydrogen molecule, \mathrm{H_2}. A bond formed by a shared pair of electrons is called a covalent bond.

Covalent bonds usually form between atoms of nonmetals.

Reaching the arrangement of a noble gas

A chlorine atom has 7 outer electrons. In a chlorine molecule, \mathrm{Cl_2}, the two atoms share one pair, and when the shared electrons are counted for both atoms, each atom has 8 outer electrons, like argon.

In a water molecule, the oxygen atom shares one pair with each of two hydrogen atoms. The oxygen atom then has 8 outer electrons, like neon, and each hydrogen atom has 2, like helium.

By sharing electrons, the atoms in a molecule usually end up with the same arrangement of electrons as a noble gas.

Lewis structures

A Lewis structure shows the outer electrons of each atom as dots around its symbol.

A pair of electrons shared between two atoms is called a shared pair, or bonding pair, and a pair that belongs to only one atom is called a lone pair.

A water molecule has 2 shared pairs and 2 lone pairs, an ammonia molecule has 3 shared pairs and 1 lone pair, and a methane molecule has 4 shared pairs and no lone pair.

Structural formulas and valency

In a structural formula, each shared pair is drawn as a single line between two atoms.

The number of covalent bonds that an atom usually forms is called its valency: 1 for hydrogen, 2 for oxygen, 3 for nitrogen and 4 for carbon.

The valency equals the number of electrons the atom needs to reach the arrangement of a noble gas, so the structural formulas of water, ammonia and methane follow directly from it.

Double and triple bonds

Two atoms can share more than one pair of electrons. Sharing two pairs makes a double bond, and sharing three pairs makes a triple bond.

There is a double bond between the oxygen atoms in \mathrm{O_2} and between the carbon atoms in ethene, \mathrm{C_2H_4}, and a carbon dioxide molecule has two double bonds.

There is a triple bond between the nitrogen atoms in \mathrm{N_2} and between the carbon atoms in ethyne, \mathrm{C_2H_2}. The more pairs two atoms share, the shorter and stronger the bond between them.

Atoms and the periodic table
Chemical bonds
Shapes and properties of molecules
Crystals